Boron

Chemical reactions


Reaction of boron with acids


Crystalline boron does not react with boiling hydrochloric acid, HCl, or boiling hydrofluoric acid, HF. Powdered boron oxidizes slowly when treated with concentrated nitric acid, HNO3.


Reaction of boron with air


Boron does not react with air at room temperature. At higher temperatures, boron reacts with oxygen, forming boron(III)oxide, B2O3.

4 B(s) + 3 O2(g) 2 B2O3(s)


Reaction of boron with halogens


Boron reacts with the halogens fluorine, chlorine and bromine, forming the respective boron(III)trihalides.

2 B(s) + 3 F2(g) 2 BF3(g)
2 B(s) + 3 Cl2(g) 2 BCl3(l)
2 B(s) + 3 Br2(g) 2 BF3(l)


Reaction of boron with water


Boron does not react with water under normal conditions.


Quantitative analysis


Method 4500-B D Inductively Coupled Plasma Method [1]. A portion of the sample is digested in a combination of acids. The digest is aspirated into an 8,000 K argon plasma where resulting light emission is quantified for 30 elements simultaneously.

Method limit of detection in water = 0.05 mg/L
Method limit of detection in soil = 1.00 mg/kg