Reaction of beryllium with acidsBeryllium is passivated by oxygen, forming a BeO surface which is resistant to acid. On a fresh surface, without the protective layer, beryllium dissolves readily in dilute acids such as sulphuric acid, H2SO4, hydrochloric acid, HCl, and nitric acid, HNO3, forming Be(II) ions and hydrogen gas, H2.
Be(s) + 2 H+(aq) Be2+(aq) + H2(g) Reaction of beryllium with airBeryllium is passivated by oxygen, forming a BeO surface. Normally beryllium cannot be oxidized, even when heating to 600 °C, but powdered beryllium can be brought to burn in air, forming beryllium oxide, BeO and beryllium nitride, Be3N2.
2 Be(s) + O2(g) 2 BeO(s) 3 Be(s) + N2(g) Be3N2(s) Reaction of beryllium with halogensBeryllium metal reacts with chlorine, Cl2 and bromine, Br2, forming the corresponding beryllium(II)dihalides.
Be(s) + Cl2(g) BeCl2(s) Be(s) + Br2(g) BeBr2(s) Reaction of beryllium with waterBeryllium does not react with water or steam, even if the metal is heated to red hot.
Quantitative analysisMethod 3500-Be C Inductively Coupled Plasma Method [1]. A portion of the sample is digested in a combination of acids. The digest is aspirated into an 8,000 K argon plasma where resulting light emission is quantified for 30 elements simultaneously.
Method limit of detection in water = 0.001 mg/L Method limit of detection in soil = 0.10 mg/kg |