Sodium

Chemical reactions


Reaction of sodium with air


Sodium reacts with air, forming sodium oxide. If heated, sodium forms sodium oxide at limited amount of oxygen and sodium peroxide at excess amount of oxygen (at 300-400 °C) [6]:

4 Na(s) + O2(g) 2 Na2O(s)
2 Na(s) + O2(g) Na2O2(s)


Reaction of sodium with halogens


Sodium reacts vigorously with halogens, forming the corresponding sodium halides:

2 Na(s) + F2(g) 2 NaF(s) [6]
2 Na(s) + Cl2(g) 2 NaCl(s)
2 Na(s) + Br2(g) 2 NaBr(s)
2 Na(s) + I2(g) 2 NaI(s)


Reaction of sodium with hydrogen


Sodium reacts with hydrogen forming sodium hydride [6]:

2 Na(s) + H2(g) 2 NaH(s)


Reaction of sodium with phosphorous


Sodium reacts with phosphorous forming sodium phosphide [6]:

12 Na(s) + P4(s) 4 Na4P(s)


Reaction of sodium with sulfur


Sodium reacts with sulfur forming sodium sulfide [6]:

16 Na(s) + S8(s) 8 Na2S(s)


Reaction of sodium with water


Sodium reacts violently with water:

2 Na(s) + 2 H2O(l) 2 Na+(aq) + 2 OH(aq) + H2(g).


Quantitative analysis


Method 3500-Na C Inductively Coupled Plasma Method [1]. A portion of the sample is digested in a combination of acids. The digest is aspirated into an 8,000 K argon plasma where resulting light emission is quantified for 30 elements simultaneously.

Method limit of detection in water = 1.0 mg/L
Method limit of detection in soil = 100.0 mg/kg