Cesium

Chemical reactions


Reaction of cesium with acids


Cesium metal dissolves readily in dilute sulphuric acid forming Cs(I) ions and hydrogen, H2.

2 Cs(s) + H2SO4(aq) 2 Cs+(aq) + SO42−(aq) + H2(g)


Reaction of cesium with air


Cesium tarnishes slowly in air as it react with both oxygen and water in the air. If burned in air, the result is mainly formation of the orange cesium superoxide, CsO2.

Cs(s) + O2(g) CsO2(s) [orange]


Reaction of cesium with halogens


Cesium reacts rigorously with all the halogens forming the corresponding cesium halides.

2 Cs(s) + F2(g) 2 CsF(s)
2 Cs(s) + Cl2(g) 2 CeCl(s)
2 Cs(s) + Br2(g) 2 CeBr(s)
2 Cs(s) + I2(g) 2 CeI(s)


Reaction of cesium with hydrogen


Cesium reacts with hydrogen, forming cesium hydride [5].

2 Cs(s) + H2(g) 2 CsH(s)


Reaction of cesium with water


Cesium reacts violently with water, forming cesium hydroxide (CsOH) and hydrogen, H2.

2 Cs(s) + 2 H2O(l) 2 CsOH(aq) + H2(g)